Canadia, Arctic Islands: projects/activities

The project aims at establishing a long-term Arctic-Antarctic network of monitoring stations for atmospheric monitoring of anthropogenic pollution. Based upon the long and excellent experiences with different scientific groups performing air monitoring within the Arctic Monitoring and Assessment Programme (AMAP), an expanded network will be established including all AMAP stations and all major Antarctic “year-around” research stations. As an integrated project within the “International Polar Year 2007-08” initiative, the ATMOPOL co-operation intend to • Establish a long-term coordinated international Arctic-Antarctic contaminant programme. • Develop and implement a joint sampling and monitoring strategy as an official guideline for all participating stations. • Support bi-polar international atmospheric research with high-quality data on atmospheric long-range transport of contaminants (sources, pathways and fate). • Support future risk assessment of contaminants for Polar Regions based on effects of relevant contamination levels and polar organisms Based upon the well-established experiences of circum-Arctic atmospheric contaminant monitoring in the Arctic under the AMAP umbrella, a bi-polar atmospheric contaminant network will be established and maintained. In conjunction with the polar network of atmospheric monitoring stations for air pollution, surface-based and satellite instrumentation will be utilised to provide the characterization of the Arctic atmospheric-water-ice cycle. Together with numerical weather prediction and chemical transport model calculations, simultaneous measurements of pollutants at various locations in the Arctic and Antarctic will enhance our understanding of chemical transport and distribution as well as their long-term atmospheric trends. In addition to investigating the importance of atmospheric transport of pollutants an understanding of the transference and impact of these pollutants on both terrestrial and marine environments will be sought. A secretariat and a “scientific project board” will be established. During this initial phase of the project (2006), a guideline on priority target compounds, sampling strategies, equipment and instrumentation, analytical requirements, as well as quality assurance protocols (including laboratory intercalibration exercises) will be developed and implemented. The ATMOPOL initiative aims to address highly relevant environmental change processes and, thus, will strive to answering the following scientific questions: • How does climate change influence the atmospheric long-range transport of pollutants? • Are environmental scientists able to fill the gaps in international pollution inventories and identification of possible sources for atmospheric pollution in Polar Regions? • What are the differences in transport pathways and distribution patterns of various atmospheric pollutants between Arctic and Antarctic environments? Why are there such differences? What is the final fate of atmospherically transported pollutants and how does this impact on the environment and indigenous people?In order to understand the underlying atmospheric chemistry of pollution, e.g. atmospheric mercury deposition events, routine surface measurements of UV radiation as well as campaign related measurements of UV radiation profiles will also be included.The project will establish a cooperative network on atmospheric contaminant monitoring in Polar Regions far beyond the IPY 2007/08 period and is, thus, planned as an “open-end” programme. All produced data will be available for all participating institutions for scientific purposes as basis for joint publications and reports from the ATMOPOL database to be developed.

The objectives of this study are to determine temporal trends of persistent organic pollutants (POPs) and metals, especially mercury, in landlocked Arctic char in Char Lake and Resolute Lake by analysis of annual sample collections, to investigate factors influencing contaminant levels in landlocked char such as the influence of sampling time, water temperature and diet, and to provide this information on a timely basis to the community of Qausuittuq (Resolute). The rationale is that small lakes in the high arctic are replenished annually with snowmelt runoff and direct precipitation which represent significant fractions of their water budgets. Declining concentrations of POPs, or increasing levels of previously unstudied POPs, in air and precipitation should be reflected relatively quickly in changes in levels in food webs and top predator fishes, compared to the vast marine environment. We know this to be the case from the sedimentary record of POPs and mercury in small arctic lakes. This project collects landlocked arctic char from lakes near Resolute annually and analyses them for mercury, a suite of other metals as well as persistent organic pollutants (PCBs, organochlorine pesticides including toxaphene). Results will be compared over time. The first samples were collected from Char and Resolute Lakes in 1992/93. The next set were collected in 1997 and annually since then. Char are being collected from several lakes in the area because of limited sample numbers in some lakes and the possibility of local influences. Samples are also being archived for future analyses.

The objectives of the project are: A) to determine temporal trends in atmospheric mercury concentrations and deposition processes of mercury in the Arctic, and to assist in the development of long-term strategies for this priority pollutant by: i) measuring ambient air Total Gaseous Mercury (TGM) concentrations in the Canadian Arctic (Alert) and investigating the linkage to elevated levels of mercury known to be present in the Arctic food chain; ii) investigating and establishing the causes of temporal variability (seasonal, annual) in mercury concentrations so that realistic representations (models) of atmospheric pathways and processes can be formulated, tested and validated; iii) studying the chemical and physical aspects of atmospheric mercury vapour transformation (oxidation) after polar sunrise and the resultant enhanced mercury deposition to the sea, snow and ice surfaces each year during springtime; and iv) obtaining a long-term time series of atmospheric mercury (TGM) concentrations at Alert for the purpose of establishing whether mercury in the troposphere of the northern hemisphere is (still) increasing and if so, at what rate; B) to establish a sound scientific basis for addressing existing gaps of knowledge of the behaviour of mercury in the Arctic environment that will enable international regulatory actions to reflect the appropriate environmental protection strategies and pollution controls for the Arctic by: i) studying the relative roles of anthropogenic and natural sources of mercury so as to clarify understanding of the atmospheric pathways leading to the availability of mercury to Arctic biota; ii) studying tropospheric TGM depletion mechanisms/processes leading to enhanced input of mercury to the Arctic biosphere in spring; iii) undertaking essential speciated measurements of particulate-phase and/or reactive gaseous-phase mercury as well as mercury in precipitation (snow/rain) to quantify wet and dry deposition fluxes into the Arctic environment; and vi) providing the scientific basis for the information and advice used in the preparation and development of Canadian international strategies and negotiating positions for appropriate international control objectives.

The objectives of this project are: A) to determine the pathway for the transfer of mercury in snowmelt to sea water during the melt period at Alert; B) to determine the extent of open water and wet ice in the summer Arctic as it affects the surface exchange of Hg using satellite radar imagery; and C) to determine the atmospheric dynamics associated with the photochemistry of mercury episodically during the polar sunrise period.